




Annoucements
New Workshop
"Preparing Graduate Students to be Scientific Leaders in a Sustainable Society"
September 4, 5, 8, and 9
The workshop is made possible by a grant from the T&J Meyer Family Foundation awarded to the Chemistry Department and the Material Science Institute
Learn more...
Or email chem@uoregon.edu for more information
Department
Email / Phone List
1253 University of Oregon
Eugene, OR 97403-1253
541-346-4601
Photo of Mt. Hood by Bernd Mohr.
WEBMASTER: chem@uoregon.edu
UO
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Latest News
July 2008
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Lallie McKenzie is given the 2008 Kenneth G. Hancock Memorial Award for green chemistry, becoming the second national winner from Jim Hutchison's green chemistry/nanotechnology laboratory (learn more) |
May 2008
Snapshots from a Journey to Aromaticity

1,2-Dihydro-1,2-azaborines are
boron-nitrogen-containing heterocycles that are isostructural to the
ubiquitous and important benzene motif. The determination of the aromatic
character of these BN-heterocycles has received substantial interest.
The Liu group has taken a structural approach
to address this issue. Eric Abbey in the Liu lab synthesized and structurally
characterized “pre-aromatic” 1,2-dihydro-1,2-azaborines,
enabling the direct comparison of localized vs. delocalized systems.
The crystallographic data provide an unprecedented look into the structural
changes that occur in six-membered BN-heterocycles on their road to
aromaticity, and they establish with little ambiguity that 1,2-dihydro-1,2-azaborines
possess delocalized structures consistent with aromaticity.
Abbey,
E. R.; Zakharov, L. N.; Liu, S.-Y. “Crystal Clear Structural Evidence
for Electron Delocalization in 1,2-Dihydro-1,2-azaborines” J.
Am. Chem. Soc. 2008, 130, ASAP.
More news... |